全文获取类型
收费全文 | 6351篇 |
免费 | 751篇 |
国内免费 | 1930篇 |
专业分类
化学 | 4356篇 |
晶体学 | 243篇 |
力学 | 2037篇 |
综合类 | 47篇 |
数学 | 329篇 |
物理学 | 2020篇 |
出版年
2024年 | 15篇 |
2023年 | 114篇 |
2022年 | 252篇 |
2021年 | 309篇 |
2020年 | 278篇 |
2019年 | 204篇 |
2018年 | 156篇 |
2017年 | 287篇 |
2016年 | 335篇 |
2015年 | 286篇 |
2014年 | 379篇 |
2013年 | 466篇 |
2012年 | 429篇 |
2011年 | 461篇 |
2010年 | 432篇 |
2009年 | 469篇 |
2008年 | 470篇 |
2007年 | 532篇 |
2006年 | 414篇 |
2005年 | 390篇 |
2004年 | 391篇 |
2003年 | 346篇 |
2002年 | 264篇 |
2001年 | 205篇 |
2000年 | 189篇 |
1999年 | 147篇 |
1998年 | 131篇 |
1997年 | 116篇 |
1996年 | 104篇 |
1995年 | 75篇 |
1994年 | 73篇 |
1993年 | 43篇 |
1992年 | 60篇 |
1991年 | 41篇 |
1990年 | 31篇 |
1989年 | 21篇 |
1988年 | 28篇 |
1987年 | 21篇 |
1986年 | 23篇 |
1985年 | 9篇 |
1984年 | 7篇 |
1983年 | 3篇 |
1982年 | 6篇 |
1981年 | 6篇 |
1979年 | 8篇 |
1978年 | 1篇 |
1974年 | 1篇 |
1971年 | 2篇 |
1957年 | 2篇 |
排序方式: 共有9032条查询结果,搜索用时 15 毫秒
101.
102.
Optical and structural properties of coumarin-4 dye-doped SiO2-PDMS xerogels synthesized by acid catalyzed (one-step) and acid-base catalyzed (two-step) sol-gel routes with varying pH (0.6 to 7) and dye content ( 5 × 10–4 to 5 × 10–2 mole) are reported. Spectroscopic methods such as photo-luminescence, FT-IR and FT-Raman were used for characterizations. The acid catalyzed xerogels prepared with pH < 2.5 exhibited two fluorescence peaks, I at 390 nm and II at 480 nm. The acid-base catalyzed xerogels synthesized with pH < 2.5 also exhibited two peaks, I at 400 nm and II at 475 nm. Peak II was not observed for the samples with pH 2.5. This phenomenon was attributed to the existence of pH dependent different forms of coumarin-4 molecule. The concentration-quenching phenomenon was observed for the acid catalyzed xerogels prepared with different dye concentration. TheFT-IR spectra indicated the existence of hydrogen bonds between the carbonyl groups of dye molecules and the silanol groups of gel matrix. The hydrogen bonding was the highest for the samples with the extremity pH, 0.6 and 7, resulting in the highest dye/gel matrix interactions, hence, the highest fluorescence peaks. The Raman studies indicated that the samples prepared with pH < 2.5 possessed relatively more number of 3-membered siloxane rings than 4-membered siloxane rings. The ring statistics was reversed for the samples with pH > 2.5. The number of silanol groups was higher for the samples with pH > 2.5. 相似文献
103.
氧化共沉淀法制备纳米级掺锑α—Fe2O3气敏陶瓷粉料 总被引:1,自引:0,他引:1
氧化共沉淀法制备纳米级掺锑α┐Fe2O3气敏陶瓷粉料王忠春**刘尔生陈耐生*黄金陵(福州大学化学系福州350002)关键词α-Fe2O3陶瓷,锑掺杂气敏材料,纳米材料1996-10-05收稿,1997-04-22修回福建省科委资助项目**现在上海硅酸... 相似文献
104.
固态电池发展至今,许多比能量高、贮存性能好的新型电池产品不断涌向市场,而目前广泛用于正极材料的大多数物质是层状化合物[1],如聚乙炔,聚苯胺等化合物,它们贮存能量的方式主要是通过插入化学反应来实现,本工作将合成一种高分子材料——2.5-二巯基-1,3... 相似文献
105.
手性液晶掺杂剂(S)┐4┐辛氧基┐4┐(2┐酰氧基┐丙氧基)联苯的合成马汝建李培荣国斌*(华东理工大学化学系上海200237)关键词铁电液晶材料,手性液晶掺杂剂,合成,手征性1997-02-03收稿,1997-08-07修回铁电液晶显示器所用的材料... 相似文献
106.
《Surface and interface analysis : SIA》2003,35(6):544-547
We have developed multiple short‐period delta layers as a reference material for SIMS ultra‐shallow depth profiling. Boron nitride delta layers and silicon spacer layers were sputter‐deposited alternately, with a silicon spacer thickness of 1–5 nm. These delta‐doped layers were used to measure the sputtering rate change in the initial stage of oxygen ion bombardment. A significant variation of sputtering rate was observed in the initial 3 nm or less. The sputtering rate in the initial 3 nm was estimated to be about four times larger than the steady‐state value for 1000 eV oxygen ions. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
107.
采用表面改性法制备了负载型光催化材料CeO2-TiO2/SiO2,并用X射线衍射,比表面积测定,红外光谱,程序升温还原和紫外可见漫反射光谱技术对固体材料的结构和光响应性能进行了表征.结果表明,CeO2与TiO2在材料表面存在相互修饰作用,CeO2能拓展TiO2的光响应范围,使TiO2吸光区域由紫外拓宽至可见光区,从而提高材料的光能利用率;Ti4 可以进入CeO2晶格,形成Ce-O-Ti键合,使得Ti4 平均配位数增加,同时提高了CeO2体相晶格氧的活性;TiO2有助于提高CeO2在载体表面的分散程度,减小CeO2的微晶尺寸,提高固体材料的能隙值和氧化还原能力. 相似文献
108.
采用溶胶-凝胶法合成了一种V2O5/C复合材料.扫描电镜(SEM)和红外光谱(FTIR)分析表明,这是一种外层V2O5胶体包覆内层乙炔分子的多孔复合材料.以V2O5/C作正极,锌片为负极,Zn(ClO4)2溶液为电解质组成水相锌二次电池,采用循环伏安(CV)和电化学阻抗谱(EIS)等方法研究发现:V2O5:C质量比为1:1时电极具有最好的电化学性能,电池开路电压达1.64 V; Zn2+能分别在1.01 V和1.26 V处分步嵌入V2O5/C结构中A、B两种位置,其嵌入电流密度峰值最高可达70 mA•g-1,并且具有较好的循环充放电性能;在一定放电深度下,V2O5/C电极反应速率受Zn2+的扩散过程控制. 相似文献
109.
锂离子电池正极材料LiMn2O4的合成与晶体结构(英) 总被引:2,自引:0,他引:2
Spinel LiMn2O4 powders were prepared using two-step synthesis method consisting of solid-state reaction method and citrate modified sol-gel method. The effects of the calcination temperature and the Li/Mn ratio of raw materials were studied on the physicochemical and electrochemical properties of the spinel LiMn2O4 powders, such as crystallinity, lattice constant and density. The title compound was characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Polycrystalline LiMn2O4 powers calcined at 750 ℃ were found to be composed of very uniformly-sized microcrystal with an average particle size of 300 nm. The improvement in electrochemical properties was mainly attributed to the process of re-grinding by absolute alcohol. 相似文献
110.
Polyethylene based composites are attractive materials for advanced circuit board applications because of their unique combination of properties: low dielectric constant and loss factor, light weight, high flexural modulus and low thermal expansion coefficient controlled in all spatial directions. This investigation describes a process to consolidate chopped fibers of ultra‐high molecular weight polyethylene concurrently with its bonding to a copper foil. Bonding is affected by a thin sheet of low‐density polyethylene, incorporating a crosslinking agent with a concentration gradient across the sheets thickness. In this single step process, the composite material is formed and bonded to the metal foil, achieving good adhesion without the use of extraneous glue. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献